Working from home has been great. Saving time from travelling to and from work, more time to sleep in, more time for family etc. But at the same time, I find that I am getting emails/calls from work colleagues even outside of working hours, sometimes with the expectation that I reply immediately even though it is after work hours or on a weekend.
Just out of curiosity, what's your experience so far?
I haven't received E-mails or calls from your work colleagues. lol
Why not set up an auto-response on your E-mail saying:
"Your E-mail has been received and will be answered during the Hours of 9-5PM, M-F"
Put your Phone on Voicemail with a similar message.
Call them back when it suits you unless it is urgent or part of your job.